Título
Study on the combustion behavior of high impact polystyrene nanocomposites produced by different extrusion processes
Autor
GUADALUPE SANCHEZ OLIVARES
Nivel de Acceso
Acceso Abierto
Materias
Resumen o descripción
The combustion behavior of a blend made of high impact polystyrene (HIPS) with sodium montmorillonite (MMT-Na+) and triphenyl phosphite (TPP), as a halogen-free flame retardant, is analyzed in detail in this work. The blend is processed through various extrusion methods aimed to improve clay dispersion. The UL94 method in vertical position, oxygen index and cone calorimetric measurements assess HIPS blend behavior in combustion. TGA, FTIR, SEM and X-ray measurements, together with mechanical and rheological tests evaluate the thermal degradation, morphology, intercalation and degree of dispersion of particles. The use of a static-mixing die placed at the extreme of a single screw extruder improves clay platelets distribution and reduces the peak heat release rate better than employing a twin screw extrusión process. In addition, mechanical and rheological properties are affected substantially by changing the extrusion process. A correlation between clay dispersion and HIPS fire retardant properties is found, as the peak heat release rate decreases with good clay dispersion in cone calorimetric tests.
Fecha de publicación
2008
Tipo de publicación
Artículo
Versión de la publicación
Versión publicada
Recurso de información
Formato
application/pdf
Idioma
Inglés
Audiencia
Empresas
Estudiantes
Investigadores
Maestros
Repositorio Orígen
Repositorio Institucional CIATEC
Descargas
168