Título

Tensile piezoresistivity and disruption of percolation in singlewall and multiwall carbon nanotube/polyurethane composites

Autor

FRANCIS AVILES CETINA

Nivel de Acceso

Acceso Abierto

Resumen o descripción

Carbon nanotube elastomeric composite films were fabricated by solution casting using singlewall

and multiwall carbon nanotubes (SWCNTs and MWCNTs) and two thermoplastic-elastomers polymer

matrices, an in-house synthesized segmented polyurethane and a commercial one. The CNTs are first

characterized and the electrical conductivity, mechanical properties and piezoresistive response of the

SWCNT and MWCNT composites with 8 wt% are evaluated. For both polymer matrices, the electrical

conductivity of composites made from MWCNTs is higher than that achieved for composites made from

SWCNTs. Evaluation of the strain–electrical resistance relationship of the composites shows a dependency

of the piezoresistive sensitivity on the kind of CNT (SWCNT or MWCNT) and matrix electrical and

mechanical properties. Above a specific strain threshold, electrical percolation is disrupted under tensile

loading. The strain level at which this happens is larger for composites made with MWCNTs than for

composites made with SWCNTs.

Fecha de publicación

6 de noviembre de 2013

Tipo de publicación

Artículo

Formato

application/pdf

Repositorio Orígen

Repositorio Institucional CICY

Descargas

1035

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