Título
Sol-gel synthesis and antioxidant properties of yttrium oxide nanocrystallites incorporating P-123
Autor
HIRAM ISAAC BELTRAN CONDE
Nivel de Acceso
Acceso Abierto
Referencia de publicación
ISSN/1996-1944
Referencia de datos
doi: 10.3390/ma7096768
Materias
Resumen o descripción
Yttrium oxide (Y2O3) nanocrystallites were synthesized by mean of a sol-gel method using two different precursors. Raw materials used were yttrium nitrate and yttrium chloride, in methanol. In order to promote oxygen vacancies, P-123 poloxamer was incorporated. Synthesized systems were heat-treated at temperatures from 700 °C to 900 °C. Systems at 900 °C were prepared in the presence and absence of P-123 using different molar ratios (P-123:Y = 1:1 and 2:1). Fourier transform infrared spectroscopy (FTIR) results revealed a characteristic absorption band of Y–O vibrations typical of Y2O3 matrix. The structural phase was analyzed by X-ray diffraction (XRD), showing the characteristic cubic phase in all systems. The diffraction peak that presented the major intensity corresponded to the sample prepared from yttrium chloride incorporating P-123 in a molar ratio of P-123:Y = 2:1 at 900 °C. Crystallites sizes were determined by Scherrer equation as between 21 nm and 32 nm. Antioxidant properties were estimated by 2,2-diphenyl-1-picrylhydrazyl (DPPH•) assays; the results are discussed
Editor
Materials 2014, 7, 6768-6778;
Fecha de publicación
2014
Tipo de publicación
Artículo
Recurso de información
Formato
application/pdf
Idioma
Inglés
Repositorio Orígen
Concentración de Recursos de Información Científica y Académica, UAM Cuajimalpa
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