Título

Near UV-blue excitable green-emitting nanocrystalline oxide

Autor

CARLOS EDUARDO RODRIGUEZ GARCIA

NESTOR PEREA LOPEZ

GUSTAVO ALONSO HIRATA FLORES

Nivel de Acceso

Acceso Abierto

Identificador alterno

doi: http://dx.doi.org/10.1155/2011/790517

Resumen o descripción

"Green-emitting Eu-activated powders were produced by a two-stage method consisting of pressure-assisted combustion synthesis and postannealing in ammonia. The as-synthesized powders exhibited a red photoluminescence (PL) peak located at  nm when excited with  nm UV. This emission peak corresponds to the 5D0→7F2 transition in Eu3+. After annealing in ammonia, the PL emission changed to an intense broad-band peak centered at  nm, most likely produced by 4f65d1→4f7 electronic transitions in Eu2+. This green-emitting phosphor has excitation band in the near UV-blue region (–450 nm). X-ray diffraction analysis reveals mainly the orthorhombic EuAlO3 and Al2O3 phases. Transmission electron microscopy observations showed that the grains are formed by faceted nanocrystals (~4 nm) of polygonal shape. The excellent excitation and emission properties make these powders very promising to be used as phosphors in UV solid-state diodes coupled to activate white-emitting lamps."

Editor

Hindawi Publishing Corporation

Fecha de publicación

2011

Tipo de publicación

Artículo

Versión de la publicación

Versión publicada

Formato

application/pdf

Idioma

Inglés

Audiencia

Público en general

Sugerencia de citación

C. E. Rodríguez-García, N. Perea-López, and G. A. Hirata. (2011). Near UV-Blue Excitable Green-Emitting Nanocrystalline Oxide. Advances in Materials Science and Engineering Volume 2011, Article ID 790517, http://dx.doi.org/10.1155/2011/790517

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Repositorio IPICYT

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