Título

Arsenic contamination in irrigation water, agricultural soil and maize crop from an abandoned smelter site in Matehuala, Mexico

Autor

ESTHER AURORA RUIZ HUERTA

ALONSO DE LA GARZA VARELA

JUAN MIGUEL GOMEZ BERNAL

Francisco Castillo-Rivera

MIGUEL AVALOS BORJA

Bhaskar Sen Gupta

NADIA VALENTINA MARTINEZ VILLEGAS

Nivel de Acceso

En Embargo

Identificador alterno

doi: https://doi.org/10.1016/j.jhazmat.2017.06.041

Resumen o descripción

"Mobility of Arsenic (As) from metallurgical wastes in Matehuala, Mexico has been accounted for ultra-high concentration of As in water (4.8–158 mg/L) that is used for recreational purposes as well as cultivation of maize. In this study, we (i) measured As concentrations in soils irrigated with this water, (ii) investigated the geochemical controls of available As, and (iii) measured bioaccumulation of As in maize. Water, soil, and maize plant samples were collected from 3 different plots to determine As in environmental matrices as well as water soluble As in soils. Soil mineralogy was determined by X-ray diffraction analysis. Bioaccumulation of As in maize plants was estimated from the bioconcentration and translocation factors. We recorded As built-up in agricultural soils to the extent of 172 mg/kg, and noted that this As is highly soluble in water (30% on average). Maize crops presented high bioaccumulation, up to 2.5 times of bioconcentration and 45% of translocation. Furthermore, we found that water extractable As was higher in soils rich in calcite, while it was lower in soils containing high levels of gypsum, but As bioconcentration showed opposite trend. Results from this study show that irrigation with As rich water represents a significant risk to the population consuming contaminated crops."

Editor

Elsevier B.V.

Fecha de publicación

octubre de 2017

Tipo de publicación

Artículo

Versión de la publicación

Versión aceptada

Formato

application/pdf

Sugerencia de citación

Esther Aurora Ruíz-Huerta, Alonso de la Garza Varela, Juan Miguel Gómez-Bernal, Francisco Castillo, Miguel Avalos-Borja, Bhaskar SenGupta, Nadia Martínez-Villegas, Arsenic contamination in irrigation water, agricultural soil and maize crop from an abandoned smelter site in Matehuala, Mexico, Journal of Hazardous Materials, Volume 339, 2017, Pages 330-339.

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