Título

Influence of protons on reduction degree and defect formation in electrochemically reduced graphene oxide

Autor

JAVIER ALAN QUEZADA RENTERIA

Ania Conchi O.

Luis Felipe Cházaro Ruiz

JOSE RENE RANGEL MENDEZ

Nivel de Acceso

Acceso Abierto

Identificador alterno

doi: https://doi.org/10.1016/j.carbon.2019.04.109

Resumen o descripción

"The electrochemical reduction of GO was investigated in aqueous, at both acid and basic pH, and organic media, to identify the possible role of protons (H+) in the reduction mechanism of this material. The obtained rGO films were characterized by FTIR, electrochemical methods, Raman and XPS spectroscopy. Data showed that the reduction was more efficient in acid and basic media due to the presence of protons and the capacity of water that works as a proton donor, resulting in C/O ratios of 3.8 and 7.8, respectively. Mostly hydroxyl, epoxide and carbonyl moieties were removed. In a proton-free organic electrolyte, a C/O ratio of 1.8 was obtained for most of the samples; nevertheless, the graphitic carbon sp2 domains were restored to a large extent in the absence of H+. The characterization of the material showed that the presence of protons, during the electrochemical reduction, caused hydrogenation reactions, which targeted the graphitic domains in rGO and resulted in the loss of sp2 hybridization. The presence of such defects modified the electrochemical properties of the rGO films, where, despite of exhibiting higher C/O ratio, the films reduced in aqueous electrolytes displayed lower electron transfer (e.g. ferrocyanide redox-probe) than those reduced in organic electrolyte."

Editor

Elsevier

Fecha de publicación

2019

Tipo de publicación

Artículo

Versión de la publicación

Versión publicada

Formato

application/pdf

Sugerencia de citación

Javier A. Quezada-Renteria, Conchi O. Ania, Luis F. Chazaro-Ruiz, Jose R. Rangel-Mendez, Influence of protons on reduction degree and defect formation in electrochemically reduced graphene oxide, Carbon, Volume 149, 2019, Pages 722-732, https://doi.org/10.1016/j.carbon.2019.04.109.

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Repositorio IPICYT

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