Título

Conductive Polymer Composites Synthesized from Diacetylene-Functionalized Linseed Oil and MWCNT: Gamma Irradiation and Organic Vapor Sensing

Autor

ALEJANDRO RAMIREZ JIMENEZ

SUSANA HERNANDEZ LOPEZ

EMILIO BUCIO CARRILLO

ENRIQUE VIGUERAS SANTIAGO

Nivel de Acceso

Acceso Abierto

Resumen o descripción

Beca de estancia de Posdoctorado del Dr. Alejandro Ramírez Jiménez

Epoxidized linseed oil (ELO) was synthesized and functionalized with propargylamine (PA) or 3-ethynylaniline (EA) and the products were crosslinked to obtain the diacetylene-functionalized epoxidized linseed oil polymers which were used as matrices in the preparation of the composites with multiwalled carbon nanotubes (MWCNTs). Electrical resistance at percentages between 4 and 20 wt/wt% of filler was measured and the percolation threshold was calculated, obtaining 1.2 and 1.7% for the composites with EA and PA respectively. Low critical concentration evidenced a good dispersion of the MWCNTs without necessity of any modification. The final products were used in the sensing of acetone, chloroform and ethanol. The electrical resistance changes were measured at different concentrations and the sensibility was calculated. In order to improve stability toward the vapors, composites were irradiated with gamma rays and new sensing was done and compared. The results showed differences in sensibility, selectivity and reproducibility.

CONACyT

Editor

Scrivener Publishing

Fecha de publicación

1 de abril de 2017

Tipo de publicación

Artículo

Fuente

2164-6325

Idioma

Inglés

Audiencia

Estudiantes

Investigadores

Repositorio Orígen

REPOSITORIO INSTITUCIONAL DE LA UAEM

Descargas

49

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