Data for the synthesis, characterization, and use of xerogels as adsorbents for the removal of fluoride and bromide in aqueous phase

NAHUM ANDRES MEDELLIN CASTILLO ELIZABETH DIANE ISAACS PAEZ Liliana Giraldo Gutiérrez JUAN CARLOS MORENO-PIRAJAN ITZIA RODRIGUEZ MENDEZ SIMON YOBANNY REYES LOPEZ JAIME REYES HERNANDEZ SONIA JUDITH SEGOVIA SANDOVAL (2022, [Artículo])

"Groundwater with high fluoride concentrations has been recognized as one of the serious concerns worldwide. Besides, the fluoride released into the groundwater by slow dissolution of fluoride-containing rocks, various industries also contribute to fluoride pollution [1]. Excess intake of fluoride leads to various health problems such as dental and skeletal fluorosis, cancer, infertility, brain damage, thyroid diseases, etc. [2]. On the other hand, bromide is naturally present in surface and groundwater sources. However, during the chlorination process, bromide can be oxidized to HOBr, which can react with natural organic matter in water to form brominated organic disinfection byproducts, which are very harmful to human health [3]. Among various methods for water treatment, the adsorption process has been widely used and seems to be an efficient and attractive method for the removal of many contaminants in water, such as anions, in terms of cost, simplicity of design, and operation [4,5]. In the past years, xerogels and carbon xerogels, a new type of adsorbents, which are synthesized by the sol-gel polycondensation of resorcinol and formaldehyde, have gained attention due to their moldable texture and chemical properties [6]. Moreover, melamine addition in resorcinol and formaldehyde xerogels adds basic groups on its surface, favouring Lewis acid-base interactions between xerogels and other components by adsorption [7]. In this data article, the synthesis of three resorcinolformaldehyde (R/F) xerogels with an increasing amount of melamine (M) was carried out by colloidal polymerization (molar ratios of M/R = 0.5, M/R = 1.0, and M/R = 2.0). Additionally, samples of M/R = 0.5 xerogel were carbonized at 400, 450, and 550 degrees C under an inert atmosphere to increase their specific area. Organic and carbon xerogels obtained were characterized by FTIR, TGA, SEM, Physisorption of N 2, and the pH at the point of zero charge (pH PZC). All organic xerogels were also tested as adsorbents on the removal of fluoride and bromide ions from aqueous phase. The Freundlich, Langmuir, and Radke-Prausnitz isotherm models were applied to interpret the experimental data from adsorption equilibrium. Additionally, the data of the mass of the xerogel needed to remove fluoride and bromide from groundwater and fulfill the maximum concentration levels are also included."

Xerogels Melamine Colloidal polymerization Fluoride and bromide ions Adsorption BIOLOGÍA Y QUÍMICA QUÍMICA QUÍMICA

Application of spheroidal agglomerates of γ-Al2O3 in the fluoride removal from aqueous medium

Aplicación de aglomerados esferoidales de γ-Al2O3 en la remoción de fluoruro de medio acuoso

RAFAEL ROMERO TOLEDO VICTOR RUIZ SANTOYO ULISES ZURITA LUNA GUSTAVO RANGEL PORRAS MERCED MARTINEZ ROSALES (2019, [Artículo])

En el presente estudio se investigó un adsorbente aglomerado esferoidal de γ-Al2O3 obtenido a partir de pseudoboehmita para la eliminación eficaz de fluoruro de un medio acuoso. Las propiedades superficiales se caracterizaron por diversas técnicas: XRD, fisisorción de N2, FE-SEM/EDS, RMN 27Al, adsorción de piridina por FT-IR, PZy tamaño de partícula. Se llevaron a cabo experimentos en lotes y se compararon con una alúmina activada comercial (AA). El proceso se llevó a cabo a pH 5, 7 y 9, a 25 y 35 ºC. Los resultados experimentales indicaron que los aglomerados esferoidales de γ-Al2O3 eliminan hasta 15 mg/g, con una capacidad de adsorción mayor que AA de 13 mg/g, a pH 5, estudiados a 25 y 35 ºC. El proceso de adsorción de F-en γ-Al2O3 y AA siguió la cinética de pseudo-primer orden y la isoterma de Langmuir. Los resultados muestran un adsorbente eficaz para la eliminación de F-.

A spheroidal agglomerate γ-Al2O3 adsorbent obtained from pseudoboehmite for effective removal of fluoride from aqueous medium was investigated in the present study. The surface properties were characterized by several techniques: XRD, physisorption of N2, FE-SEM/EDS, 27Al NMR, FT-IR Pyridine adsorption, PZ and particle size. Batch experiments were conducted and they were compared with a commercial activated alumina (AA). The process was carried out at pH 5, 7, and 9, then at 25 and 35 ºC. Batch experimental results indicated that the spheroidal agglomerates of γ-Al2O3 remove up to 15 mg/g with a higher adsorption capacity than AA of 13 mg/g, at pH 5, studied at 25 and 35 °C. The F−adsorption processes in γ-Al2O3 and AA followed the pseudo-first-order kinetics and the Langmuir isotherm. The results showed an adsorbent effective for removal of F−.

BIOLOGÍA Y QUÍMICA Fluoride γ-Al2O3 Spheroidal agglomerates Adsorbent Water Fluoruro γ-Al2O3 Aglomerados esferoidales Adsorbentes Agua

Phenotypic assessment of genetic gain from selection for improved drought tolerance in semi-tropical maize populations

Terence Molnar Somak Dutta Thanda Dhliwayo Samuel Trachsel Michael Lee (2023, [Artículo])

Drought Tolerant Population Topcross Water Deficit CIENCIAS AGROPECUARIAS Y BIOTECNOLOGÍA DROUGHT TOLERANCE WATER MAIZE CLIMATE CHANGE GENETIC GAIN

Appraisal of complementarity of subsurface drip fertigation and conservation agriculture for physiological performance and water economy of maize

C.M. Parihar Hari Sankar Nayak Dipaka Ranjan Sena Renu Pandey Mahesh Gathala ML JAT (2023, [Artículo])

The Indo-Gangetic Plains (IGP) in north-west (NW) India are facing a severe decline in ground water due to prevalent rice-based cropping systems. To combat this issue, conservation agriculture (CA) with an alternative crop/s, such as maize, is being promoted. Recently, surface drip fertigation has also been evaluated as a viable option to address low-nutrient use efficiency and water scarcity problems for cereals. While the individual benefits of CA and sub-surface drip (SSD) irrigation on water economy are well-established, information regarding their combined effect in cereal-based systems is lacking. Therefore, we conducted a two-year field experiment in maize, under an ongoing CA-based maize-wheat system, to evaluate the complementarity of CA with SSD irrigation through two technological interventions–– CA+ (residue retained CA + SSD), PCA+ (partial CA without residue + SSD) – at different N rates (0, 120 and 150 kg N ha-1) in comparison to traditional furrow irrigated (FI) CA and conventional tillage (CT) at 120 kg N ha-1. Our results showed that CA+ had the highest grain yield (8.2 t ha-1), followed by PCA+ (8.1 t ha-1). The grain yield under CA+ at 150 kg N ha-1 was 27% and 30% higher than CA and CT, respectively. Even at the same N level (120 kg N ha-1), CA+ outperformed CA and CT by 16% and 18%, respectively. The physiological performance of maize also revealed that CA+ based plots with 120 kg N ha-1 had 12% and 3% higher photosynthesis rate at knee-high and silking, respectively compared to FI-CA and CT. Overall, compared to the FI-CA and CT, SSD-based CA+ and PCA+ saved 54% irrigation water and increased water productivity (WP) by more than twice. Similarly, a greater number of split N application through fertigation in PCA+ and CA+ increased agronomic nitrogen use efficiency (NUE) and recover efficiency by 8–19% and 14–25%, respectively. Net returns from PCA+ and CA+ at 150 kg N ha-1 were significantly higher by US$ 491 and 456, respectively than the FI-CA and CT treatments. Therefore, CA coupled with SSD provided tangible benefits in terms of yield, irrigation water saving, WP, NUE and profitability. Efforts should be directed towards increasing farmers’ awareness of the benefits of such promising technology for the cultivating food grains and commercial crops such as maize. Concurrently, government support and strict policies are required to enhance the system adaptability.

Net Returns Subsurface Drip Irrigation Subsurface Drip Fertigation CIENCIAS AGROPECUARIAS Y BIOTECNOLOGÍA EFFICIENCY GRAIN NITROGEN PHOTOSYNTHESIS PHYSIOLOGY WATER SUPPLY CONSERVATION AGRICULTURE CONVENTIONAL TILLAGE FERTIGATION GROUNDWATER NITROGEN-USE EFFICIENCY WATER PRODUCTIVITY

Diseño y evaluación bioclimática para Museo del Agua en el municipio de Tecámac, Estado de México

Luis Roberto Gómez Luna (2023, [Otro, Trabajo terminal, especialidad])

155 páginas. Especialización en Diseño Ambiental.

El propósito de ésta idónea comunicación de resultados (ICR) es compartir la metodología aplicada para la aplicación de diseño bioclimático desde el diseño de un proyecto nuevo además de aplicarla en un museo para el organismo público descentralizado para la prestación de los servicios de agua potable, alcantarillado y saneamiento (ODAPAS) con la temática del agua desde su tratamiento, usos, historia, y la parte que conforman en la cultura de Tecámac. Se explica a detalle las estrategias aplicadas para lograr el confort acústico, lumínico, térmico, y de ventilación, especificando la metodología del diseño bioclimático aplicada, así como los resultados de estas.

Museum architecture. Museum buildings. Architecture and climate. Water conservation. Visual education. Arquitectura de museos. Edificios de museos. Conservación del agua. Educación visual. Arquitectura y clima. NA6690 HUMANIDADES Y CIENCIAS DE LA CONDUCTA CIENCIAS DE LAS ARTES Y LAS LETRAS ARQUITECTURA DISEÑO ARQUITECTÓNICO

Cascading socio-environmental sustainability risks of agricultural export miracle in Peru

Azam Lashkari Masoud Irannezhad Urs Schulthess (2022, [Artículo])

Andean Trade Preference Act Alternative Development CIENCIAS AGROPECUARIAS Y BIOTECNOLOGÍA DEVELOPMENT GROUNDWATER SUSTAINABILITY WATER SCARCITY

Trade-off in the design of sustainable cropping systems at a regional level: A case study on the North China plain

Jeroen Groot XiaoLin Yang (2022, [Artículo])

Holistic Analysis Model-Based Analysis CIENCIAS AGROPECUARIAS Y BIOTECNOLOGÍA CROP ROTATION FOOD SECURITY WATER USE ENVIRONMENTAL PROTECTION ECONOMIC VIABILITY

Bundling subsurface drip irrigation with no-till provides a window to integrate mung bean with intensive cereal systems for improving resource use efficiency

Manish Kakraliya madhu choudhary Mahesh Gathala Parbodh Chander Sharma ML JAT (2024, [Artículo])

The future of South Asia’s major production system (rice–wheat rotation) is at stake due to continuously aggravating pressure on groundwater aquifers and other natural resources which will further intensify with climate change. Traditional practices, conventional tillage (CT) residue burning, and indiscriminate use of groundwater with flood irrigation are the major drivers of the non-sustainability of rice–wheat (RW) system in northwest (NW) India. For designing sustainable practices in intensive cereal systems, we conducted a study on bundled practices (zero tillage, residue mulch, precise irrigation, and mung bean integration) based on multi-indicator (system productivity, profitability, and efficiency of water, nitrogen, and energy) analysis in RW system. The study showed that bundling conservation agriculture (CA) practices with subsurface drip irrigation (SDI) saved ~70 and 45% (3-year mean) of irrigation water in rice and wheat, respectively, compared to farmers’ practice/CT practice (pooled data of Sc1 and Sc2; 1,035 and 318 mm ha−1). On a 3-year system basis, CA with SDI scenarios (mean of Sc5–Sc8) saved 35.4% irrigation water under RW systems compared to their respective CA with flood irrigation (FI) scenarios (mean of Sc3 and Sc4) during the investigation irrespective of residue management. CA with FI system increased the water productivity (WPi) and its use efficiency (WUE) by ~52 and 12.3% (3-year mean), whereas SDI improved by 221.2 and 39.2% compared to farmers practice (Sc1; 0.69 kg grain m−3 and 21.39 kg grain ha−1 cm−1), respectively. Based on the 3-year mean, CA with SDI (mean of Sc5–Sc8) recorded −2.5% rice yield, whereas wheat yield was +25% compared to farmers practice (Sc1; 5.44 and 3.79 Mg ha−1) and rice and wheat yield under CA with flood irrigation were increased by +7 and + 11%, compared to their respective CT practices. Mung bean integration in Sc7 and Sc8 contributed to ~26% in crop productivity and profitability compared to farmers’ practice (Sc1) as SDI facilitated advancing the sowing time by 1 week. On a system basis, CA with SDI improved energy use efficiency (EUE) by ~70% and partial factor productivity of N by 18.4% compared to CT practices. In the RW system of NW India, CA with SDI for precise water and N management proved to be a profitable solution to address the problems of groundwater, residue burning, sustainable intensification, and input (water and energy) use with the potential for replication in large areas in NW India.

Direct Seeded Rice Subsurface Drip Irrigation Economic Profitability Energy and Nitrogen Efficiency CIENCIAS AGROPECUARIAS Y BIOTECNOLOGÍA CONSERVATION AGRICULTURE RICE SUBSURFACE IRRIGATION IRRIGATION SYSTEMS WATER PRODUCTIVITY ECONOMIC VIABILITY ENERGY EFFICIENCY NITROGEN-USE EFFICIENCY

Expanding the WOFOST crop model to explore options for sustainable nitrogen management: A study for winter wheat in the Netherlands

João Vasco Silva Pytrik Reidsma (2024, [Artículo])

Nitrogen (N) management is essential to ensure crop growth and to balance production, economic, and environmental objectives from farm to regional levels. This study aimed to extend the WOFOST crop model with N limited production and use the model to explore options for sustainable N management for winter wheat in the Netherlands. The extensions consisted of the simulation of crop and soil N processes, stress responses to N deficiencies, and the maximum gross CO2 assimilation rate being computed from the leaf N concentration. A new soil N module, abbreviated as SNOMIN (Soil Nitrogen for Organic and Mineral Nitrogen module) was developed. The model was calibrated and evaluated against field data. The model reproduced the measured grain dry matter in all treatments in both the calibration and evaluation data sets with a RMSE of 1.2 Mg ha−1 and the measured aboveground N uptake with a RMSE of 39 kg N ha−1. Subsequently, the model was applied in a scenario analysis exploring different pathways for sustainable N use on farmers' wheat fields in the Netherlands. Farmers' reported yield and N fertilization management practices were obtained for 141 fields in Flevoland between 2015 and 2017, representing the baseline. Actual N input and N output (amount of N in grains at harvest) were estimated for each field from these data. Water and N-limited yields and N outputs were simulated for these fields to estimate the maximum attainable yield and N output under the reported N management. The investigated scenarios included (1) closing efficiency yield gaps, (2) adjusting N input to the minimum level possible without incurring yield losses, and (3) achieving 90% of the simulated water-limited yield. Scenarios 2 and 3 were devised to allow for soil N mining (2a and 3a) and to not allow for soil N mining (2b and 3b). The results of the scenario analysis show that the largest N surplus reductions without soil N mining, relative to the baseline, can be obtained in scenario 1, with an average of 75%. Accepting negative N surpluses (while maintaining yield) would allow maximum N input reductions of 84 kg N ha−1 (39%) on average (scenario 2a). However, the adjustment in N input for these pathways, and the resulting N surplus, varied strongly across fields, with some fields requiring greater N input than used by farmers.

Crop Growth Models WOFOST CIENCIAS AGROPECUARIAS Y BIOTECNOLOGÍA CROPS NITROGEN-USE EFFICIENCY WINTER WHEAT SOIL WATER

Conservation agriculture based sustainable intensification: India updates

ML JAT (2021, [Objeto de congreso])

CIENCIAS AGROPECUARIAS Y BIOTECNOLOGÍA CONSERVATION AGRICULTURE SUSTAINABLE INTENSIFICATION LAND MANAGEMENT TILLAGE PLANT ESTABLISHMENT BIOMASS WATER MANAGEMENT