EFFICIENT FLUORESCENT AND PHOSPHORESCENT OLEDs BY SPIN COATING TECHNIQUE AND A NEW ANODE BASED ON CONDUCTIVE PEDOT:PSS

Luis Abraham Lozano Hernández (2020, [Tesis de doctorado])

"Fluorescent and phosphorescent Organic Light Emitting Diode (OLED) devices were fabricated by solution process and optimized. From their basic characterization (J-V-L curves, electroluminescence spectra) external quantum efficiency (EQE) was calculated. Two small molecule, carbazole derivatives (CZ-1 and CZ-2), previously reported and used for OLEDs showed very good luminances (~ 4000 cd/m2) and current densities (< 200 mA/cm2) resulting in a high EQE (9.5 %). Likewise, fluorescent OLEDs based in the new polymer PF-2F presented an acceptable performance even on a simple architecture with a good EQE (2.6 %), photoluminescence quantum yield (PLQY) about 1 and excellent properties of processability. The influence of its CF3 group in the optical, chemical, electronic and mechanical properties in OLEDs was determined.

Also, a new family of three fluorescent oligomers (BT-F32, BT-F42 and BT-F52) with excellent properties in solution, high PLQY (~1) and highly luminescent, were used in simple and multilayer OLEDs achieving a very high luminance (29 499 cd/m2). These oligomers have different chain lengths, which influence the device luminance, efficiency and their lifetime. Lifetime was monitored and the stretched exponential decay (SED) model was used in order to obtain the device half-life (LT50). Also, phosphorescent devices, based on a host/guest system (PVK:Ir(ppy)3), were prepared, the influence of the electron transport layer (ETL) into the electron/hole ratio was analyzed.

By using a new proposed method, a PEDOT:PSS anode was developed and applied in rigid and flexible substrates, with low sheet resistance (40 Ω/□) and acceptable transmittance (> 85%). This new proposed method consists in volume evaporation, in which basically the loss of water induces closeness among the conductive fractions of PEDOT. This PEDOT:PSS anode easy of fabricating following an economical procedure could be applied not just in OLEDs but in other optoelectronic devices such as organic photovoltaic cells (OPVs), perovskite solar cells (PeSCs), etc."

OLEDs Fluorescence Phosphorescence PEDOT:PSS Polymer Anode INGENIERÍA Y TECNOLOGÍA CIENCIAS TECNOLÓGICAS TECNOLOGÍA ELECTRÓNICA DISPOSITIVOS SEMICONDUCTORES DISPOSITIVOS SEMICONDUCTORES

The Chemical Evolution of Narrow Emission Line Galaxies: the Key to their Formation Processes

JUAN PABLO TORRES PAPAQUI ROGER COZIOL RENE ALBERTO ORTEGA MINAKATA (2011, [Artículo])

Using the largest sample of narrow emission line galaxies available so far, we show that their spectral characteristics are correlated with different physical parameters, like the chemical abundances, the morphologies, the masses of the bulge and the mean stellar age of the stellar populations of the host galaxies. It suggests that the spectral variations observed in standard spectroscopic diagnostic diagrams are not due solely to variations of ionization parameters or structures but reflect also the chemical evolution of the galaxies, which in turn can be explained by different galaxy formation processes.

Utilizando la mayor muestra de galaxias con líneas de emisión angostas disponible hasta el momento, se muestra que sus características espectrales están correlacionadas con diferentes parámetros físicos, como las abundancias químicas, las morfologías, las masas del bulbo, y la edad estelar promedio de las poblaciones estelares de la galaxia anfitrio-na. Por lo tanto, se sugiere que las variaciones espectrales observadas en diagramas de diagnóstico estándares no se deben únicamente a las variaciones de los parámetros o las estructuras de ionización, sino que reflejan también la evolución química de las galaxias, relacionada con diferentes procesos de formación

CIENCIAS FÍSICO MATEMÁTICAS Y CIENCIAS DE LA TIERRA Galaxy Chemical Activity Formation Chemical evolution Galaxias Actividad química Formación Evolución química

Complex traits and candidate genes: estimation of genetic variance components across multiple genetic architectures

GIOVANNY COVARRUBIAS-PAZARAN Hans-Peter Piepho (2023, [Artículo])

Average Semivariance Linear Mixed Model Variance Component Estimation Polygenic Inheritance Oligogenic Inheritance Mendelian Inheritance CIENCIAS AGROPECUARIAS Y BIOTECNOLOGÍA MENDELISM GENETIC VARIANCE GENOME-WIDE ASSOCIATION STUDIES PHENOTYPES CHROMOSOME MAPPING

Women, economic resilience, gender norms in a time of climate change: what do we know?

Cathy Farnworth Anne Rietveld Rachel Voss Angela Meentzen (2023, [Artículo])

This literature delves into 82 research articles, published between 2016 and 2022, to develop a deep understanding of how women manage their lives and livelihoods within their agrifood systems when these systems are being affected, sometimes devastatingly, by climate change. The Findings show that four core gender norms affect the ability of women to achieve economic resilience in the face of climate change operate in agrifood production systems. Each of these gender norms speaks to male privilege: (i) Men are primary decision-makers, (ii) Men are breadwinners, (iii) Men control assets, and (iv) Men are food system actors. These gender norms are widely held and challenge women’s abilities to become economically resilient. These norms are made more powerful still because they fuse with each other and act on multiple levels, and they serve to support other norms which limit women’s scope to act. It is particularly noteworthy that many institutional actors, ranging from community decision-makers to development partners, tend to reinforce rather than challenge gender norms because they do not critically review their own assumptions.

However, the four gender norms cited are not hegemonic. First, there is limited and intriguing evidence that intersectional identities can influence women’s resilience in significant ways. Second, gender norms governing women’s roles and power in agrifood systems are changing in response to climate change and other forces, with implications for how women respond to future climate shocks. Third, paying attention to local realities is important – behaviours do not necessarily substantiate local norms. Fourth, women experience strong support from other women in savings groups, religious organisations, reciprocal labour, and others. Fifth, critical moments, such as climate disasters, offer potentially pivotal moments of change which could permit women unusually high levels of agency to overcome restrictive gender norms without being negatively sanctioned. The article concludes with recommendations for further research.

Economic Resilience Intersectional Identities Women Groups Support CIENCIAS AGROPECUARIAS Y BIOTECNOLOGÍA ECONOMICS RESILIENCE CLIMATE CHANGE GENDER NORMS AGRIFOOD SYSTEMS WOMEN

Data for the synthesis, characterization, and use of xerogels as adsorbents for the removal of fluoride and bromide in aqueous phase

NAHUM ANDRES MEDELLIN CASTILLO ELIZABETH DIANE ISAACS PAEZ Liliana Giraldo Gutiérrez JUAN CARLOS MORENO-PIRAJAN ITZIA RODRIGUEZ MENDEZ SIMON YOBANNY REYES LOPEZ JAIME REYES HERNANDEZ SONIA JUDITH SEGOVIA SANDOVAL (2022, [Artículo])

"Groundwater with high fluoride concentrations has been recognized as one of the serious concerns worldwide. Besides, the fluoride released into the groundwater by slow dissolution of fluoride-containing rocks, various industries also contribute to fluoride pollution [1]. Excess intake of fluoride leads to various health problems such as dental and skeletal fluorosis, cancer, infertility, brain damage, thyroid diseases, etc. [2]. On the other hand, bromide is naturally present in surface and groundwater sources. However, during the chlorination process, bromide can be oxidized to HOBr, which can react with natural organic matter in water to form brominated organic disinfection byproducts, which are very harmful to human health [3]. Among various methods for water treatment, the adsorption process has been widely used and seems to be an efficient and attractive method for the removal of many contaminants in water, such as anions, in terms of cost, simplicity of design, and operation [4,5]. In the past years, xerogels and carbon xerogels, a new type of adsorbents, which are synthesized by the sol-gel polycondensation of resorcinol and formaldehyde, have gained attention due to their moldable texture and chemical properties [6]. Moreover, melamine addition in resorcinol and formaldehyde xerogels adds basic groups on its surface, favouring Lewis acid-base interactions between xerogels and other components by adsorption [7]. In this data article, the synthesis of three resorcinolformaldehyde (R/F) xerogels with an increasing amount of melamine (M) was carried out by colloidal polymerization (molar ratios of M/R = 0.5, M/R = 1.0, and M/R = 2.0). Additionally, samples of M/R = 0.5 xerogel were carbonized at 400, 450, and 550 degrees C under an inert atmosphere to increase their specific area. Organic and carbon xerogels obtained were characterized by FTIR, TGA, SEM, Physisorption of N 2, and the pH at the point of zero charge (pH PZC). All organic xerogels were also tested as adsorbents on the removal of fluoride and bromide ions from aqueous phase. The Freundlich, Langmuir, and Radke-Prausnitz isotherm models were applied to interpret the experimental data from adsorption equilibrium. Additionally, the data of the mass of the xerogel needed to remove fluoride and bromide from groundwater and fulfill the maximum concentration levels are also included."

Xerogels Melamine Colloidal polymerization Fluoride and bromide ions Adsorption BIOLOGÍA Y QUÍMICA QUÍMICA QUÍMICA

Chemically modified nanoparticles for enhanced antioxidant and antimicrobial properties with cinnamon essential oil

Aaron Azael Lopez Cano VERONICA MARTINEZ AGUILAR Mariana Peña-Juárez Ricardo López Esparza Enrique Delgado Alvarado Emmanuel Gutierrez MAYRA DEL ANGEL MONROY Elias Perez Agustin L. Herrera-May JOSE AMIR GONZALEZ CALDERON (2023, [Artículo])

We explored the potential of different nanoparticles (TiO2, CaCO3, and Al2O3), considering their pure form and modified with cinnamon essential oil (CEO). These materials were characterized using various techniques, including FTIR spectroscopy, XRD analysis, TGA, and SEM. The interaction between CEO and nanoparticles changed depending on the nanoparticle type. Al2O3 nanoparticles exhibited the strongest interaction with CEO, increasing their antioxidant capacity by around 40% and their transfer of antimicrobial properties, particularly against Gram-negative bacteria. In contrast, TiO2 and CaCO3 nanoparticles showed limited interaction with CEO, resulting in lower antioxidant capacity and antimicrobial activity. Incorporating pure and CEO-modified nanoparticles into polylactic acid (PLA) films improved their mechanical and thermal properties, which are suitable for applications requiring greater strength. This research highlights the potential of metal oxide nanoparticles to enhance the antimicrobial and antioxidant capabilities of polymers. In addition, incorporating cinnamon essential oil can increase the antioxidant and antimicrobial effectiveness of the metal oxide nanoparticles and improve the mechanical and thermal properties of PLA films. Thus, these PLA films exhibit favorable characteristics for active packaging applications.

Author contributions: conceptualization, V.M.-A. and J.A.G.-C.; formal analysis, A.A.L.-C., V.M.-A., M.G.P.-J. and M.D.A.-M.; funding acquisition, A.L.H.-M.; methodology, A.A.L.-C. and V.M.-A.; investigation, E.P.; supervision, R.L.-E., E.D.-A., and E.J.G.-C.; validation, A.L.H.-M. and J.A.G.-C.; writing—original draft, V.M.-A.; writing—review and editing, M.G.P.-J. and J.A.G.-C. All authors have read and agreed to the published version of the manuscript.

Funding: J.A. Gonzalez-Calderon thanks CONAHCYT for supporting the Catedras-CONAHCYT Program, and Verónica Martinez thanks CONAHCYT for the Doctoral Fellowship. The authors also want to thank CONAHCYT for funding the project CF2019 265239 “Ciencia de Frontera”, which made this work possible.

Institutional review board statement: Not applicable.

Informed consent statement: Not applicable.

Data availability statement: Data is contained within the article.

Acknowledgments: The authors acknowledge Claudia Hernández and Rosa Lina Tovar for their support during the XRD and SEM analyses.

Conflicts of interest: The authors declare no conflict of interest.

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Cinnamon essential oil Antioxidant activity Antimicrobial properties Nanoparticles Polylactic acid films INGENIERÍA Y TECNOLOGÍA CIENCIAS TECNOLÓGICAS OTRAS ESPECIALIDADES TECNOLÓGICAS OTRAS OTRAS

Molecular characterization of doubled haploid lines derived from different cycles of the Iowa Stiff Stalk Synthetic (BSSS) maize population

Jode Edwards Sarah Hearne (2023, [Artículo])

Homozygous Lines CIENCIAS AGROPECUARIAS Y BIOTECNOLOGÍA GENETIC DIVERSITY (AS RESOURCE) GENETIC RESOURCES ZEA MAYS GENOTYPING DOUBLED HAPLOIDS SINGLE NUCLEOTIDE POLYMORPHISMS

Entre la solidaridad y el capital: niveles de subsunción de las experiencias de economía popular

EDUARDO ENRIQUE AGUILAR HERNANDEZ (2023, [Artículo])

"El presente trabajo abona al debate sobre la disputa conceptual y de sentido de las economías populares. Este proceso de reflexión está fundamentado en los resultados de entrevistas semiestructuradas y la observación participante de proyectos de economía popular en Jalisco, que analizo mediante categorías de economía política para comprender los diferentes niveles de subsunción al sistema de producción capitalista. Como conclusión del trabajo, visibilizo que, dentro del ámbito material, las experiencias de economía popular con mayor composición orgánica de capital, como la cooperativa llantera, tienen una subsunción real al sistema, mientras que aquellas iniciativas de baja composición, como las iniciativas agroecológicas, están subsumidas a éste de manera formal".

CIENCIAS SOCIALES CIENCIAS ECONÓMICAS ACTIVIDAD ECONÓMICA COMERCIO INTERIOR COMERCIO INTERIOR

Plan de medidas preventivas y de mitigación de la sequía en la cuenca del río Balsas

ISRAEL VELASCO VELASCO DAVID ORTEGA GAUCIN (2014, [Documento de trabajo])

Tabla de contenido: Introducción – Caracterización de la cuenca del río Balsas – Análisis de las sequías históricas y sus impactos – Análisis de la vulnerabilidad ante la sequía – Etapas, indicadores y umbrales de la sequía – Medidas preventivas y de mitigación de la sequía – Programa de respuesta a las etapas de la sequía – Sistema de seguimiento y evaluación.

A partir de series históricas y datos hidrométricos y climatológicos, se realizó el análisis de las sequías históricas y sus impactos, además de evaluar la vulnerabilidad ante la sequía en las distintas regiones de la cuenca del río Balsas. Posteriormente se determinaron una serie de acciones que pueden ser implementadas en el marco del Consejo de Cuenca, con objeto de afrontar la sequía en tres sentidos: antes de que ocurra el fenómeno (medidas estratégicas); cuando apenas inicia (medidas tácticas); y cuando ya está presente (medidas de emergencia). Las medidas pueden ser de corto, mediano o largo plazos. Su consideración está en función de la intensidad del fenómeno, de los impactos que cause y de los recursos disponibles para invertir. Muchas de las medidas propuestas en este documento son de tipo estructural y necesarias para ahorrar agua y recuperar volúmenes. No obstante, como se ha visto históricamente y es una realidad, gran parte de los efectos de la sequía son consecuencias derivadas de las fallas en la gestión del agua. Razón por la cual el informe incluye, además, una serie detallada de acciones para administrar el riesgo de sequía y afrontar el fenómeno en sus distintas etapas, desde moderada hasta excepcional.

Introducción – Caracterización de la cuenca del río Balsas – Análisis de las sequías históricas y sus impactos – Análisis de la vulnerabilidad ante la sequía – Etapas, indicadores y umbrales de la sequía – Medidas preventivas y de mitigación de la sequía – Programa de respuesta a las etapas de la sequía – Sistema de seguimiento y evaluación.

Informes de proyectos Sequías Impacto ambiental Aspectos económicos Prevención y mitigación Río Balsas CIENCIAS FÍSICO MATEMÁTICAS Y CIENCIAS DE LA TIERRA

Estrategia para mejorar e implementar procesos y modelos de negocio en tarimas y embalajes Dipisur

FRANCISCO JAVIER ACOSTA VALERO (2023, [Tesis de maestría])

A través de este documento, podremos conocer la estrategia utilizada ante las problemáticas de tarimas y embalajes Dipisur, a su vez, conoceremos un modelo de negocio eficiente, con el cuál la empresa, podrá operar los próximos años sin ningún problema, teniendo en cuenta, el rumbo y la finalidad del trabajo,

Apoyaremos a que la misión, visión y valores, sean la bandera con la cuál se trabaje siempre, y que tener metas claras, y objetivos que cumplir sean lo que mueva a este proyecto a mejoras continuas.

Maestría en Administración Empresarial

CIENCIAS SOCIALES CIENCIAS ECONÓMICAS ORGANIZACIÓN Y DIRECCIÓN DE EMPRESAS DIRECCIÓN DE VENTAS