Title

Further mulinane and azorellane diterpenoids isolated from Mulinum crassifolium and Azorella compacta

Author

LUIS MANUEL PEÑA RODRIGUEZ

GLORIA MARIA MOLINA SALINAS

Access level

Open Access

License

http://creativecommons.org/licenses/by-nc-nd/4.0

Dataset reference

doi: DOI: 10.3390/molecules19043898

Subjects

MULINANES - (AUTORES) AZORELLANES - (AUTORES) NEW DITERPENOIDS - (AUTORES) CHILEAN NATIVE PLANTS - (AUTORES) BIOLOGÍA Y QUÍMICA - (CTI)

Summary or description

The new mulinane diterpenoids 1 and 2 were isolated from the EtOAc extract of Mulinum crassifolium, while the rearranged mulinane 5, which was isolated for the first time from a natural source, was isolated from Azorella compacta. Compounds 1-2 were prepared by semi-synthesis thorough acetylation of the diterpene 17-acetoxymulinic acid (3). A mechanism of reaction was proposed, while the structures of the new compounds were elucidated on the basis of comprehensive spectroscopic analysis and computational methods.

Publish date

2014

Publication type

Article

Publication version

Published Version

Information Resource

http://cicy.repositorioinstitucional.mx/jspui/handle/1003/543

Format

application/pdf

Source

Molecules, 19(4), 3898-3908, 2014

Language

English

Relation

&

Simirgiotis, M. J. (2014). Further mulinane and azorellane diterpenoids isolated from mulinum crassifolium and azorella compacta. Molecules, 19(4), 3898-3908.

Citation suggestion

Bórquez, J., Ardiles, A., Loyola, L. A., Peña-Rodriguez, L. M., Molina-Salinas, G. M., Vallejos, J., ...

Source repository

Repositorio Institucional CICY

Downloads

210