Further mulinane and azorellane diterpenoids isolated from Mulinum crassifolium and Azorella compacta
LUIS MANUEL PEÑA RODRIGUEZ
GLORIA MARIA MOLINA SALINAS
doi: DOI: 10.3390/molecules19043898
Summary or description
The new mulinane diterpenoids 1 and 2 were isolated from the EtOAc extract of Mulinum crassifolium, while the rearranged mulinane 5, which was isolated for the first time from a natural source, was isolated from Azorella compacta. Compounds 1-2 were prepared by semi-synthesis thorough acetylation of the diterpene 17-acetoxymulinic acid (3). A mechanism of reaction was proposed, while the structures of the new compounds were elucidated on the basis of comprehensive spectroscopic analysis and computational methods.
Molecules, 19(4), 3898-3908, 2014
Simirgiotis, M. J. (2014). Further mulinane and azorellane diterpenoids isolated from mulinum crassifolium and azorella compacta. Molecules, 19(4), 3898-3908.
Bórquez, J., Ardiles, A., Loyola, L. A., Peña-Rodriguez, L. M., Molina-Salinas, G. M., Vallejos, J., ...
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