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Thermal and mechanical properties of PLA-based multiscale cellulosic biocomposites

MIGUEL ANGEL RUZ CRUZ Pedro Jesús Herrera Franco Emmanuel Alejandro Flores Johnson MARIA VERONICA MORENO CHULIM LUCIANO MIGUEL GALERA MANZANO Alex Valadez González (2022, [Artículo])

In this work polylactic acid (PLA) based multiscale cellulosic biocomposites were prepared with the aim to evaluate the effect of the incorporation of cellulose nanocrystals (CNCs) on the PLA biocomposites reinforced with cellulose microfibers (MFCs). For this, PLA composite materials reinforced with both MFCs and with a combination of MFCs and CNCs were prepared, while keeping the content of cellulosic reinforcements constant. The thermal and mechanical properties of these multiscale PLA biocomposites were characterized by thermogravimetry (TGA), differential scanning calorimetry (DSC), flexural mechanical and, dynamic mechanical (DMA) tests. Likewise, they were characterized by Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The results show that the replacement of MFCs by CNCs in the 1–5% range appreciably modifies the thermal and mechanical properties of multiscale compounds. For example, they increase the thermal stability of the materials, modify the PLA crystallization process and play the role of adhesion promoters since the mechanical properties in flexure increase in the order of 40% and the storage modulus increases in the order of 35% at room temperature. Also, the addition of CNCs increases the relaxation temperature of the material from 50 to 60 °C, thereby expanding the temperature range for its use. © 2022 The Author(s)

MULTISCALE BIOCOMPOSITES CELLULOSE MICROFIBER CELLULOSE NANOCRYSTALS HIERARCHICAL STRUCTURE PROPERTIES INGENIERÍA Y TECNOLOGÍA CIENCIAS TECNOLÓGICAS TECNOLOGÍA DE MATERIALES PROPIEDADES DE LOS MATERIALES PROPIEDADES DE LOS MATERIALES

Producción de energía en un reactor bio-electroquímico generador de hidrógeno

Edson Baltazar Estrada Arriaga OSCAR GUADARRAMA PEREZ JESUS HERNANDEZ ROMANO (2017, [Ítem publicado en memoria de congreso])

En este estudio se investigó el arranque de un reactor bio-electroquímico para la generación simultánea de electricidad y bio-hidrógeno a través de la degradación de sucrosa como fuente de carbono. El reactor fue sometido a diferentes inóculos y operado con un tiempo de residencia hidráulica de 8 d con una temperatura de 32°C. El voltaje máximo generado usando una resistencia externa de 1,000 Ω fue de 671 mV. La máxima densidad de potencia y volumétrica obtenida en el sMER-H2 fue de 46 mW/m2 y 6.4 W/m3. La velocidad máxima de producción de bio-hidrógeno fue de 5.2 L H2/L·d. con rendimientos de hasta 2.39 mol H2/mol sucrosa. La aplicación de esta nueva configuración de reactor bio-electroquímico generó electricidad y bio-hidrogeno en un solo paso.

Electricidad Reactores bioelectroquímicos INGENIERÍA Y TECNOLOGÍA

Development of a thermoelectric test for electrical contactors

PABLO OROZCO CORRAL FRANCISCO JAVIER IBARRA VILLEGAS NOE VILLA VILLASEÑOR (2023, [Artículo])

In the economic model in which we develop, there is a dependence on the means of transport that every day is increasing and due to the importance of electrification in the issue of efficient and clean transportation, has caused the need for companies supplying components for automotive manufacturers to evolve and develop new technologies to stay ahead of the needs of their customers being in full evolution towards electrified transport. This evolution extends not only to manufacturing but to the test methods that currently exist, since automotive standards require suppliers to test in laboratory, the components they sell to their customers to ensure their correct operation.

Electrical contactors Powered thermal cycle endurance Busbars Electrification industry INGENIERÍA Y TECNOLOGÍA CIENCIAS TECNOLÓGICAS OTRAS ESPECIALIDADES TECNOLÓGICAS OTRAS OTRAS

Impact of manures and fertilizers on yield and soil properties in a rice-wheat cropping system

Alison Laing Akbar Hossain (2023, [Artículo])

The use of chemical fertilizers under a rice-wheat cropping system (RWCS) has led to the emergence of micronutrient deficiency and decreased crop productivity. Thus, the experiment was conducted with the aim that the use of organic amendments would sustain productivity and improve the soil nutrient status under RWCS. A three-year experiment was conducted with different organic manures i.e. no manure (M0), farmyard manure@15 t ha-1 (M1), poultry manure@6 t ha-1(M2), press mud@15 t ha-1(M3), rice straw compost@6 t ha-1(M4) along with different levels of the recommended dose of fertilizer (RDF) i.e. 0% (F1), 75% (F2 and 100% (F3 in a split-plot design with three replications and plot size of 6 m x 1.2 m. Laboratory-based analysis of different soil as well as plant parameters was done using standard methodologies. The use of manures considerably improved the crop yield, macronutrients viz. nitrogen, phosphorus, potassium and micronutrients such as zinc, iron, manganese and copper, uptake in both the crops because of nutrient release from decomposed organic matter. Additionally, the increase in fertilizer dose increased these parameters. The system productivity was maximum recorded under F3M1 (13,052 kg ha-1) and results were statistically identical with F3M2 and F3M3. The significant upsurge of macro and micro-nutrients in soil and its correlation with yield outcomes was also observed through the combined use of manures as well as fertilizers. This study concluded that the use of 100% RDF integrated with organic manures, particularly farmyard manure would be a beneficial resource for increased crop yield, soil nutrient status and system productivity in RWCS in different regions of India.

CIENCIAS AGROPECUARIAS Y BIOTECNOLOGÍA ORGANIC FERTILIZERS YIELDS SOIL PROPERTIES RICE WHEAT CROPPING SYSTEMS

Generación de energía eléctrica a partir del tratamiento de aguas residuales por medio de bioceldas

EDSON BALTAZAR ESTRADA ARRIAGA (2013, [Documento de trabajo])

Actualmente, la recuperación de bioenergía (electricidad, metano e hidrógeno) a través de las aguas residuales, ya sean de origen industrial o municipal, ha despertado un gran interés en la comunidad científica. En este informe, se presenta la forma como la bioconversión de la material orgánica presente en el agua residual puede generar energía eléctrica y a su vez reducir la carga orgánica de las aguas residuales.

Energía eléctrica Tratamiento de aguas residuales Celdas de combustible microbianas Informes de proyectos INGENIERÍA Y TECNOLOGÍA

Influence of novel coconut oil and beeswax edible coating and MAP on postharvest shelf life and quality attributes of lemon at low temperature

Mohammad Mainuddin Molla Ashfak Ahmed Sabuz Md Abdul Matin (2023, [Artículo])

Weight loss, turning of peel colour from green to yellow and microbial infections are the major postharvest problems of lemon. Lipid-based edible coatings and modified atmospheric packaging (MAP) are effective techniques in maintaining postharvest quality of fruits for long-term storage. With this view, an investigation was conducted for the preservation of green lemon using coconut oil and beeswax edible coating and MAP during storage at low temperature. Physiologically matured lemons were collected and washed with potable water; fruit surface water was removed and then coated with coconut oil-beeswax (90:10) or only coconut oil. After coating, lemons were packaged in MAP or kept in open crates and stored at 12±1 °C and 85±5% relative humidity (RH) for 8 weeks and a week interval, the sampling was conducted. The results revealed that coconut oil-beeswax coating had immense effect on retaining shiny green colour, reducing respiration, weight loss, shrivelling and preserving firmness and ascorbic acid of lemon throughout the storage. On the other hand, MAP mainly helped to retain moisture & firmness and reduce shrivelling. Uncoated lemons kept open lost the highest amount of ascorbic acid and retained only 13.7 mg/100 g that is significantly (p < 0.05) less than the lemons of all other treatments at 8th week of storage period. While lemons coated with coconut oil-beeswax and packaged in MAP was preserved the highest amount (24.2 mg/100 g) of ascorbic acid and there was no significant difference (p < 0.05) with the amount of ascorbic acid content of lemons coated with only coconut oil and packaged in MAP at the last week (8th week) of storage. Hue angle value was 93.4 in uncoated lemons packaged in MAP while it was 113.67 in coconut oil-beeswax coated lemon kept open and 112.64 in lemon coated with coconut oil-beeswax and packaged in MAP at 8th week of storage. Based on all sensory, physical and chemical parameters uncoated lemons kept open was acceptable up to 1 week, coconut oil-beeswax coated lemon kept open was 6 weeks and coconut oil-beeswax coated lemon packaged in MAP was 8 weeks with good quality and shiny green colour.

Edible Coating Sensory Quality Hue Angle Yellowing CIENCIAS AGROPECUARIAS Y BIOTECNOLOGÍA EDIBLE FILMS RESPIRATION RATE LEMONS MODIFIED ATMOSPHERE PACKAGING COLD

Chemically modified nanoparticles for enhanced antioxidant and antimicrobial properties with cinnamon essential oil

Aaron Azael Lopez Cano VERONICA MARTINEZ AGUILAR Mariana Peña-Juárez Ricardo López Esparza Enrique Delgado Alvarado Emmanuel Gutierrez MAYRA DEL ANGEL MONROY Elias Perez Agustin L. Herrera-May JOSE AMIR GONZALEZ CALDERON (2023, [Artículo])

We explored the potential of different nanoparticles (TiO2, CaCO3, and Al2O3), considering their pure form and modified with cinnamon essential oil (CEO). These materials were characterized using various techniques, including FTIR spectroscopy, XRD analysis, TGA, and SEM. The interaction between CEO and nanoparticles changed depending on the nanoparticle type. Al2O3 nanoparticles exhibited the strongest interaction with CEO, increasing their antioxidant capacity by around 40% and their transfer of antimicrobial properties, particularly against Gram-negative bacteria. In contrast, TiO2 and CaCO3 nanoparticles showed limited interaction with CEO, resulting in lower antioxidant capacity and antimicrobial activity. Incorporating pure and CEO-modified nanoparticles into polylactic acid (PLA) films improved their mechanical and thermal properties, which are suitable for applications requiring greater strength. This research highlights the potential of metal oxide nanoparticles to enhance the antimicrobial and antioxidant capabilities of polymers. In addition, incorporating cinnamon essential oil can increase the antioxidant and antimicrobial effectiveness of the metal oxide nanoparticles and improve the mechanical and thermal properties of PLA films. Thus, these PLA films exhibit favorable characteristics for active packaging applications.

Author contributions: conceptualization, V.M.-A. and J.A.G.-C.; formal analysis, A.A.L.-C., V.M.-A., M.G.P.-J. and M.D.A.-M.; funding acquisition, A.L.H.-M.; methodology, A.A.L.-C. and V.M.-A.; investigation, E.P.; supervision, R.L.-E., E.D.-A., and E.J.G.-C.; validation, A.L.H.-M. and J.A.G.-C.; writing—original draft, V.M.-A.; writing—review and editing, M.G.P.-J. and J.A.G.-C. All authors have read and agreed to the published version of the manuscript.

Funding: J.A. Gonzalez-Calderon thanks CONAHCYT for supporting the Catedras-CONAHCYT Program, and Verónica Martinez thanks CONAHCYT for the Doctoral Fellowship. The authors also want to thank CONAHCYT for funding the project CF2019 265239 “Ciencia de Frontera”, which made this work possible.

Institutional review board statement: Not applicable.

Informed consent statement: Not applicable.

Data availability statement: Data is contained within the article.

Acknowledgments: The authors acknowledge Claudia Hernández and Rosa Lina Tovar for their support during the XRD and SEM analyses.

Conflicts of interest: The authors declare no conflict of interest.

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Cinnamon essential oil Antioxidant activity Antimicrobial properties Nanoparticles Polylactic acid films INGENIERÍA Y TECNOLOGÍA CIENCIAS TECNOLÓGICAS OTRAS ESPECIALIDADES TECNOLÓGICAS OTRAS OTRAS

Synthesis of hollow carbon spheres by chemical activation of carbon nanoparticles for their use in electrochemical capacitor

Cesar Eduardo Sanchez Rodriguez EDUARDO TOVAR MARTINEZ MARISOL REYES REYES Luis Felipe Cházaro Ruiz ROMAN LOPEZ SANDOVAL (2022, [Artículo])

"Naphthalene combustion has been used to synthesize grams per hour of solid carbon spheres (CS). The carbon soot was activated by acid treatment consisting in a mixture of HNO3 and H2SO4 (1/3 v/v) to produce hollow carbon spheres (HCS). The effect of two concentrations of CSs (5 and 10 mg mL−1) in the acid mixture, on the physicochemical properties of the activated HCSs was studied. The HSCs were subjected to a thermal treatment to increase their graphitization to enhance their electrical conductivity. High-resolution transmission electron microscopy confirmed the formation of HCSs due to the acid treatment whereas FTIR spectra showed that the chemical activation produced functional groups on the carbon spheres surface and the heat treatment effect to remove some of them as well. A specific surface area of 300 m2 g−1 and a large density of micropores for the acid-treated CSs as well as the heat-treated CSs were estimated by analysis of N2 adsorption-desorption isotherms. A specific capacitance 70 F g−1 was calculated by cyclic voltammetry of the acid and thermally treated HCSs at 5 mV s−1, for both CS concentrations, indicating the possibility of synthesizing these HCSs using a simple method in large quantities for their use in electrochemical capacitors."

Physicochemical properties Carbon nanoparticles Chemical activation Electrochemical capacitor BIOLOGÍA Y QUÍMICA QUÍMICA QUÍMICA

Stability of FeVO4-II under Pressure: A First-Principles Study

PRICILA BETBIRAI ROMERO VAZQUEZ SINHUE LOPEZ MORENO Daniel Errandonea (2022, [Artículo])

"In this work, we report first-principles calculations to study FeVO4 in the CrVO4-type (phase II) structure under pressure. Total-energy calculations were performed in order to analyze the structural parameters, the electronic, elastic, mechanical, and vibrational properties of FeVO4-II up to 9.6 GPa for the first time. We found a good agreement in the structural parameters with the experimental results available in the literature. The electronic structure analysis was complemented with results obtained from the Laplacian of the charge density at the bond critical points within the Quantum Theory of Atoms in Molecules methodology. Our findings from the elastic, mechanic, and vibrational properties were correlated to determine the elastic and dynamic stability of FeVO4-II under pressure. Calculations suggest that beyond the maximum pressure covered by our study, this phase could undergo a phase transition to a wolframite-type structure, such as in CrVO4 and InVO4."

FeVO4 under pressure CrVO4-type structure First-principles Mechanical properties Vibrational properties Electronic properties CIENCIAS FÍSICO MATEMÁTICAS Y CIENCIAS DE LA TIERRA FÍSICA FÍSICA DEL ESTADO SÓLIDO CRISTALOGRAFÍA CRISTALOGRAFÍA

Estimating lime requirements for tropical soils: Model comparison and development

Fernando Aramburu Merlos João Vasco Silva Frédéric Baudron Robert Hijmans (2023, [Artículo])

Acid tropical soils may become more productive when treated with agricultural lime, but optimal lime rates have yet to be determined in many tropical regions. In these regions, lime rates can be estimated with lime requirement models based on widely available soil data. We reviewed seven of these models and introduced a new model (LiTAS). We evaluated the models’ ability to predict the amount of lime needed to reach a target change in soil chemical properties with data from four soil incubation studies covering 31 soil types. Two foundational models, one targeting acidity saturation and the other targeting base saturation, were more accurate than the five models that were derived from them, while the LiTAS model was the most accurate. The models were used to estimate lime requirements for 303 African soil samples. We found large differences in the estimated lime rates depending on the target soil chemical property of the model. Therefore, an important first step in formulating liming recommendations is to clearly identify the soil property of interest and the target value that needs to be reached. While the LiTAS model can be useful for strategic research, more information on acidity-related problems other than aluminum toxicity is needed to comprehensively assess the benefits of liming.

Exchangeable Acidity Aluminum Saturation Calcium Carbonate Equivalent CIENCIAS AGROPECUARIAS Y BIOTECNOLOGÍA CHEMICOPHYSICAL PROPERTIES LIMES TROPICAL ZONES ACID SOILS ALUMINIUM BASE SATURATION CALCIUM CARBONATE