Título

Synthesis, microstructural characterization and optical properties of undoped, V and Sc doped ZnO thin films

Autor

PATRICIA AMEZAGA MADRID

WILBER ANTUNEZ FLORES

JOSE ERNESTO LEDEZMA SILLAS

J GUADALUPE MURILLO RAMIREZ

OSCAR OMAR SOLIS CANTO

OSCAR EDGARDO VEGA BECERRA

MARIO MIKI YOSHIDA

Nivel de Acceso

Acceso Abierto

Resumen o descripción

Many semiconductor oxides (ZnO, TiO2, SnO2) when doped with a low percentage of non-magnetic (V, Sc) or magnetic 3d (Co, Mn, Ni, Fe) cation behave ferromagnetically. They have attracted a great deal of interest due to the integration of semiconducting and magnetic properties in a material. ZnO is one of the most promising materials to carry out these tasks in view of the fact that it is optically transparent and has n or p type conductivity. Here, we report the synthesis, microstructural characterization and optical properties of undoped, V and Sc doped zinc oxide thin films. ZnO based thin films with additions of V and Sc were deposited by the Aerosol Assisted Chemical Vapour Deposition method. V and Sc were incorporated separately in the precursor solution. The films were uniform, transparent and non-light scattering. The microstructure of the films was characterized by Grazing Incidence X-ray Diffraction, Scanning Electron Microscopy, and Scanning Probe Microscopy. Average grain size and surface rms roughness were estimated by the measurement of Atomic Force Microscopy. The microstructure of doped ZnO thin films depended on the type and amount of dopant material incorporated. The optical properties were determined from specular reflectance and transmittance spectra. Results were analyzed to determine the optical constant and band gap of the films. An increase in the optical band gap with the content of Sc dopant was obtained.

Fecha de publicación

2011

Tipo de publicación

Artículo

Versión de la publicación

Versión enviada

Formato

application/pdf

Idioma

Inglés

Repositorio Orígen

Fuente de Objetos Científicos Open Access

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318

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