Título

Hydrogen Production by Steam Reforming of Ethanol over a Ru/Al2O3 Catalyst

Autor

ALEJANDRO LOPEZ ORTIZ

MIGUEL ANGEL ESCOBEDO BRETADO

VIRGINIA HIDALINA COLLINS MARTINEZ

Nivel de Acceso

Acceso Abierto

Resumen o descripción

The present work aims the evaluation of a ruthenium catalyst supported on alumina (Ru/Al2O3) in the reforming of

ethanol for the production of hydrogen. The selection of a suitable synthesis method, support and appropriate

reagents proportions, play a major role in the catalyst performance within this reaction. Catalyst was synthesized by

the incipient impregnation method from a solution of Ruthenium (III) chloride mono-hydrated to get a loading of

10% W, and deposited on α-alumina as support. The catalyst was characterized by: X-ray diffraction (XRD), surface

area (BET), scanning electron microscopy (SEM) and a thermogravimetric analysis (TGA). The evaluation of the

catalyst was carried out using a bench-scale fixed bed reactor system for the reforming of ethanol and reaction

product compositions followed by gas chromatography. Preliminary results indicate that catalyst selectivity was

highly dependent on reaction temperature, steam to ethanol ratio and space velocity for the production of a high

content hydrogen gas product accompanied with low carbon deposition on the catalyst surface

Fecha de publicación

2012

Tipo de publicación

Memoria de congreso

Versión de la publicación

Versión enviada

Formato

application/pdf

Idioma

Inglés

Repositorio Orígen

Fuente de Objetos Científicos Open Access

Descargas

583

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