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Preparation and characterization of strongly sulfonated acid block and random copolymer membranes for acetic acid esterification with 2-Propanol

Verónica Rosiles González Ronan Le Lagadec ARELLY PAULINA VARGUEZ CATZIM María Isabel de los Dolores Loría Bastarrachea Abigail Gonzalez Diaz EMANUEL HERNANDEZ NUÑEZ Manuel de Jesús Aguilar Vega MARIA ORTENCIA GONZALEZ DIAZ (2022, [Artículo])

In this paper, we report the synthesis of block and random copolymers of 2-acrylamido-2-methyl-1-propane sulfonic acid (AMPS) and methyl methacrylate (MMA), with different AMPS feed ratios. These solution-processable copolymers with strongly sulfonated acid groups resulted in membranes with tunable ion exchange (IEC) and water absorption capacities. AFM images confirmed the microphase separation of PAMPS-b-PMMA-1:1 block copolymer membrane, annealed under the appropriate conditions. The resulting copolymers from the random combination of a 1:1 molar ratio of AMPS and MMA monomers are effective at enhancing the esterification conversion of acetic acid, when compared with a reaction catalyzed by PAMPS-b-PMMA block copolymers and the previously studied catalytic membranes. With the PAMPS-co-PMMA-1:1 membrane, the esterification reaction using acetic acid achieved 85% isopropyl acetate. These results are closely correlated with the increase in IEC (2.63 mmol H+ g−1 ) and the relationship between weight loss (20.3%) and swelling degree (68%) in 2-propanol. © 2022 by the authors. Licensee MDPI, Basel, Switzerland.

BLOCK COPOLYMERS RANDOM COPOLYMERS CATALYTIC MEMBRANES ESTERIFICATION ISOPROPYL ACETATE INGENIERÍA Y TECNOLOGÍA CIENCIAS TECNOLÓGICAS TECNOLOGÍA DE MATERIALES PROPIEDADES DE LOS MATERIALES PROPIEDADES DE LOS MATERIALES

Síncrono / asíncrono. Convergencia y alternancia en la enseñanza futura del diseño

Francisco Gerardo Toledo Ramirez (2023, [Capítulo de libro])

La cuarentena sanitaria de los últimos dos años (COVID-19) obligó a “rediseñar”, “digitalizar” o “virtualizar” nuestros cursos y estilos de enseñanza en tiempo récord para “adaptarlas” al “formato virtual a distancia” (online). La profusión de comillas en las líneas anteriores tiene la intención de señalar el carácter incierto o erróneo que ciertos términos-fetiche adquirieron en el proceso. Es importante desmitificar esas figuras de la expresión que se elevaron casi al nivel de pseudo-epistemes (presuntamente novedosas) para la enseñanza del Diseño. Ese tema lo abordo con mayor amplitud en una nueva investigación, recientemente registrada en la UAM. En este texto esbozo (en forma algo lúdica) pero seria y breve a la vez, la conveniencia de tal desmitificación y avanzo en el delineamiento de un modelo de la alternancia y convergencia de recursos pedagógico-didácticos síncronos y asíncronos, mediante la tecnología-red digital, como un elemento estratégico para la educación futura en Diseño.

The health quarantine of the last 2 years (COVID-19) forced us to “redesign”, “digitize” or “virtualize” our courses and teaching styles in record time to “adapt” them to the “virtual format” “at a distance” (online). The profusion of quotation marks in the previous lines is intended to indicate the uncertain or erroneous character that certain fetish-terms acquired in the process. It is important to demystify those figures of expression that have risen almost to the level of pseudo-epistemes (presumably novel) for teaching design. I address this topic more fully in a new investigation, recently registered at the UAM. In this text I outline (in a somewhat playful way) but serious and brief at the same time, the convenience of such “demystification” and I advance in the outline of a model of alternation and convergence of synchronous and asynchronous pedagogical-didactic resources, through technology. -digital network, as a strategic element for future design education.

Síncrono, asíncrono, virtualidad, presencialidad, diseño, remoto. Synchronous, asynchronous, virtuality, face-to-face, design, remote. Design--Study and teaching, Higher. Distance education. Blended learning. Universidad Autónoma Metropolitana. Unidad Azcapotzalco. División de Ciencias y Artes para el Diseño. Artes gráficas. Educación a Distancia. Aprendizaje combinado. NK1170 HUMANIDADES Y CIENCIAS DE LA CONDUCTA CIENCIAS DE LAS ARTES Y LAS LETRAS

Regional analysis of the wage discrimination in the indigenous workers in Mexico

Christian De la Luz-Tovar SIBYL ITALIA PINEDA SALAZAR (2023, [Artículo, Artículo])

The objective of this research is to estimate and decompose the wage gap between indigenous and non-indigenous workers by region in Mexico, to examine whether there are regional differences in the existing wage inequality that a priori affects the indigenous population and whether these differences can be attributed to the job profile of this group or by systematic labor discrimination against them. Using the data from the 2018 National Household Expenditure Revenue Survey (ENIGH-N) and the Oaxaca-Blinder decomposition, it was found that indigenous workers face a wage gap in all regions of the county. But, this gap is more pronounced in the center and south regions, where, on average, the associated component with labor discrimination has a percentage greater than 56. In contrast, in the north-central and northern regions of Mexico, the residual component is on average less than 33%, which suggests that the wage gap is explained by differences in productivity between groups.                         

Labor economics Ethnicity wage gap Indigenous population Regions Oaxaca-Blinder decomposition Economía laboral Brecha salarial étnica Población indígena Regiones Descomposición de Oaxaca-Blinder CIENCIAS SOCIALES CIENCIAS SOCIALES