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Application of spheroidal agglomerates of γ-Al2O3 in the fluoride removal from aqueous medium

Aplicación de aglomerados esferoidales de γ-Al2O3 en la remoción de fluoruro de medio acuoso

RAFAEL ROMERO TOLEDO VICTOR RUIZ SANTOYO ULISES ZURITA LUNA GUSTAVO RANGEL PORRAS MERCED MARTINEZ ROSALES (2019, [Artículo])

En el presente estudio se investigó un adsorbente aglomerado esferoidal de γ-Al2O3 obtenido a partir de pseudoboehmita para la eliminación eficaz de fluoruro de un medio acuoso. Las propiedades superficiales se caracterizaron por diversas técnicas: XRD, fisisorción de N2, FE-SEM/EDS, RMN 27Al, adsorción de piridina por FT-IR, PZy tamaño de partícula. Se llevaron a cabo experimentos en lotes y se compararon con una alúmina activada comercial (AA). El proceso se llevó a cabo a pH 5, 7 y 9, a 25 y 35 ºC. Los resultados experimentales indicaron que los aglomerados esferoidales de γ-Al2O3 eliminan hasta 15 mg/g, con una capacidad de adsorción mayor que AA de 13 mg/g, a pH 5, estudiados a 25 y 35 ºC. El proceso de adsorción de F-en γ-Al2O3 y AA siguió la cinética de pseudo-primer orden y la isoterma de Langmuir. Los resultados muestran un adsorbente eficaz para la eliminación de F-.

A spheroidal agglomerate γ-Al2O3 adsorbent obtained from pseudoboehmite for effective removal of fluoride from aqueous medium was investigated in the present study. The surface properties were characterized by several techniques: XRD, physisorption of N2, FE-SEM/EDS, 27Al NMR, FT-IR Pyridine adsorption, PZ and particle size. Batch experiments were conducted and they were compared with a commercial activated alumina (AA). The process was carried out at pH 5, 7, and 9, then at 25 and 35 ºC. Batch experimental results indicated that the spheroidal agglomerates of γ-Al2O3 remove up to 15 mg/g with a higher adsorption capacity than AA of 13 mg/g, at pH 5, studied at 25 and 35 °C. The F−adsorption processes in γ-Al2O3 and AA followed the pseudo-first-order kinetics and the Langmuir isotherm. The results showed an adsorbent effective for removal of F−.

BIOLOGÍA Y QUÍMICA Fluoride γ-Al2O3 Spheroidal agglomerates Adsorbent Water Fluoruro γ-Al2O3 Aglomerados esferoidales Adsorbentes Agua

Análisis de velocidad de soldadura robotizada para proceso MIG en acero1045 AISI

Carlos Eduardo Hernández Acero (2022, [Tesis de maestría])

Esta investigación denominada “análisis de velocidad de soldadura robotizada para proceso MIG en acero 1045 AISI” busca el desarrollo de un modelo matemático que permita, mediante parámetros conocidos, el cálculo de la penetración de soldadura en piezas unidas con proceso Metal Inert Gas (MIG). El objetivo se centra en buscar la combinación de valores paramétricos para la velocidad de soldadura, el voltaje y la corriente, los que se obtienen mediante la aplicación de un diseño experimental, que, ejecutadas en el proceso, pueda lograr una penetración de soldadura aceptable para la unión de la pieza. El modelo de superficie de respuesta aplicado fue un diseño de experimentos 2k con diseño central compuesto, y posteriormente el modelo se utilizó para estimar la velocidad de soldadura. Este diseño de experimentos se ejecutó por medio del programa estadístico Minitab versión 17. (Hernández Acero et al., 2022). Una vez teniendo la penetración de soldadura deseada en la pieza, se puede calcular la velocidad de soldadura necesaria para el cálculo de tiempo ciclo y utilizar los parámetros definidos de corriente y voltaje. Los valores de estos factores serán útiles para comenzar la programación del robot ya con la celda funcional y reducir el tiempo de arranque en automático (Hernández Acero et al., 2022).

This research, named “robotic welding speed analysis for MIG process in 1045 AISI steel”, seeks to develop a mathematical model that allow, through know parameters, the calculation of welding penetration in parts joined with Metal Inert Gas (MIG) process. The objective is focused on finding the combination of parametric values for robot welding speed, voltage and current, which are obtained through the application of a design of experiments, which, executed in the process, can achieve an acceptable welding penetration for the union of the part. The response surface model applied was a 2k design of experiments with central composite design, and subsequently the model was used to estimate the welding speed. This design of experiments was obtained using the statistical software Minitab version 17. (Hernández Acero et al., 2022). Once having the desired welding penetration in the part, it can calculate the welding speed necessary for the cycle time calculation and use the defined parameters of current and voltage to start programming the robot with the functional cell and reduce the time of startup (Hernández Acero et al., 2022).

Soldadura MIG Penetración Tiempo ciclo Velocidad de soldadura MIG welding Penetration Cycle time Welding speed INGENIERÍA Y TECNOLOGÍA CIENCIAS TECNOLÓGICAS OTRAS ESPECIALIDADES TECNOLÓGICAS OTRAS OTRAS

Diseño y evaluación bioclimática para Museo del Agua en el municipio de Tecámac, Estado de México

Luis Roberto Gómez Luna (2023, [Otro, Trabajo terminal, especialidad])

155 páginas. Especialización en Diseño Ambiental.

El propósito de ésta idónea comunicación de resultados (ICR) es compartir la metodología aplicada para la aplicación de diseño bioclimático desde el diseño de un proyecto nuevo además de aplicarla en un museo para el organismo público descentralizado para la prestación de los servicios de agua potable, alcantarillado y saneamiento (ODAPAS) con la temática del agua desde su tratamiento, usos, historia, y la parte que conforman en la cultura de Tecámac. Se explica a detalle las estrategias aplicadas para lograr el confort acústico, lumínico, térmico, y de ventilación, especificando la metodología del diseño bioclimático aplicada, así como los resultados de estas.

Museum architecture. Museum buildings. Architecture and climate. Water conservation. Visual education. Arquitectura de museos. Edificios de museos. Conservación del agua. Educación visual. Arquitectura y clima. NA6690 HUMANIDADES Y CIENCIAS DE LA CONDUCTA CIENCIAS DE LAS ARTES Y LAS LETRAS ARQUITECTURA DISEÑO ARQUITECTÓNICO

The fate of rice crop residues and context-dependent greenhouse gas emissions: Model-based insights from Eastern India

Sonam Sherpa virender kumar Andrew Mcdonald (2024, [Artículo])

Crop residue burning is a common practice in many parts of the world that causes air pollution and greenhouse gas (GHG) emissions. Regenerative practices that return residues to the soil offer a ‘no burn’ pathway for addressing air pollution while building soil organic carbon (SOC). Nevertheless, GHG emissions in rice-based agricultural systems are complex and difficult to anticipate, particularly in production contexts with highly variable hydrologic conditions. Here we predict long-term net GHG fluxes for four rice residue management strategies in the context of rice-wheat cropping systems in Eastern India: burning, soil incorporation, livestock fodder, and biochar. Estimations were based on a combination of Tier 1, 2, and 3 modelling approaches, including 100-year DNDC simulations across three representative soil hydrologic categories (i.e., dry, median, and wet). Overall, residue burning resulted in total direct GHG fluxes of 2.5, 6.1, and 8.7 Mg CO2-e in the dry, median, and wet hydrologic categories, respectively. Relative to emissions from burning (positive values indicate an increase) for the same dry to wet hydrologic categories, soil incorporation resulted in a −0.2, 1.8, or 3.1 Mg CO2-e change in emissions whereas use of residues for livestock fodder increased emissions by 2.0, 2.1, or 2.3 Mg CO2-e. Biochar reduced emissions relative to burning by 2.9 Mg CO2-e in all hydrologic categories. This study showed that the production environment has a controlling effect on methane and, therefore, net GHG balance. For example, wetter sites had 2.8–4.0 times greater CH4 emissions, on average, than dry sites when rice residues were returned to the soil. To effectively mitigate burning without undermining climate change mitigation goals, our results suggest that geographically-target approaches should be used in the rice-based systems of Eastern India to incentivize the adoption of regenerative ‘no burn’ residue management practices.

Soil Carbon Rice Residue Burning Life Cycle Assessment CIENCIAS AGROPECUARIAS Y BIOTECNOLOGÍA SOIL CARBON RICE LIFE CYCLE GREENHOUSE GASES CLIMATE CHANGE

Appraisal of complementarity of subsurface drip fertigation and conservation agriculture for physiological performance and water economy of maize

C.M. Parihar Hari Sankar Nayak Dipaka Ranjan Sena Renu Pandey Mahesh Gathala ML JAT (2023, [Artículo])

The Indo-Gangetic Plains (IGP) in north-west (NW) India are facing a severe decline in ground water due to prevalent rice-based cropping systems. To combat this issue, conservation agriculture (CA) with an alternative crop/s, such as maize, is being promoted. Recently, surface drip fertigation has also been evaluated as a viable option to address low-nutrient use efficiency and water scarcity problems for cereals. While the individual benefits of CA and sub-surface drip (SSD) irrigation on water economy are well-established, information regarding their combined effect in cereal-based systems is lacking. Therefore, we conducted a two-year field experiment in maize, under an ongoing CA-based maize-wheat system, to evaluate the complementarity of CA with SSD irrigation through two technological interventions–– CA+ (residue retained CA + SSD), PCA+ (partial CA without residue + SSD) – at different N rates (0, 120 and 150 kg N ha-1) in comparison to traditional furrow irrigated (FI) CA and conventional tillage (CT) at 120 kg N ha-1. Our results showed that CA+ had the highest grain yield (8.2 t ha-1), followed by PCA+ (8.1 t ha-1). The grain yield under CA+ at 150 kg N ha-1 was 27% and 30% higher than CA and CT, respectively. Even at the same N level (120 kg N ha-1), CA+ outperformed CA and CT by 16% and 18%, respectively. The physiological performance of maize also revealed that CA+ based plots with 120 kg N ha-1 had 12% and 3% higher photosynthesis rate at knee-high and silking, respectively compared to FI-CA and CT. Overall, compared to the FI-CA and CT, SSD-based CA+ and PCA+ saved 54% irrigation water and increased water productivity (WP) by more than twice. Similarly, a greater number of split N application through fertigation in PCA+ and CA+ increased agronomic nitrogen use efficiency (NUE) and recover efficiency by 8–19% and 14–25%, respectively. Net returns from PCA+ and CA+ at 150 kg N ha-1 were significantly higher by US$ 491 and 456, respectively than the FI-CA and CT treatments. Therefore, CA coupled with SSD provided tangible benefits in terms of yield, irrigation water saving, WP, NUE and profitability. Efforts should be directed towards increasing farmers’ awareness of the benefits of such promising technology for the cultivating food grains and commercial crops such as maize. Concurrently, government support and strict policies are required to enhance the system adaptability.

Net Returns Subsurface Drip Irrigation Subsurface Drip Fertigation CIENCIAS AGROPECUARIAS Y BIOTECNOLOGÍA EFFICIENCY GRAIN NITROGEN PHOTOSYNTHESIS PHYSIOLOGY WATER SUPPLY CONSERVATION AGRICULTURE CONVENTIONAL TILLAGE FERTIGATION GROUNDWATER NITROGEN-USE EFFICIENCY WATER PRODUCTIVITY